Nonequilibrium Nondissipative Thermodynamics: With Application to Low-pressure Diamond Synthesis: v. 68 (Springer Series in Chemical Physics)

This book provides a framework for analysing complex systems for which classical thermodynamics is often not applicable. Since the success of the activated process in 1970, diamond growth with simultaneous graphite etching under low pressure has often been regarded as a violation of the second law of thermodynamics. A series of nonequilibrium phase diagrams, which agree excellently with the activated diamond experiments, have been calculated by the author and his coworkers on the basis of reaction coupling. The book goes on to demonstrate how these lead to a complete new systematization of modern thermodynamics.